HuagongsheHuagongshe Chemistry Print Report · For research reference only
2-Methylundecanal → HCID 67985127, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 2-Methylundecanal | HCID 61031 | — |
| Reactant | (4-Methoxybenzyl)(triphenyl)phosphonium bromide | HCID 2734885 | — |
| Solvent | Tetrahydrofuran | HCID 8028 | — |
| Product | HCID 67985127 | HCID 67985127 | 53% |
Reaction Steps
Starting from (4-methoxyphenyl)methyltriphenylphosphonium bromide (6.00 g, 13.0 mmol, 1.0 equiv.), KtBuO (14 mL, 14.2 mmol, 1.1 equiv., 1M in THF) and 2-methylundecanal (2.86 g, 15.5 mmol, 1.2 equiv.), 1.98 g (53%) of the title compound was obtained after purification by flash chromatography on SiO2 (hexane/EtOAc 99:1) as a colorless oil.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US09193935B2 |
| Source dataset | uspto-grants-2015_11 |
| ORD ID | ord-19f6f74f88e14896bef9725313ec74d1 |
| Source note | uspto-grants-2015_11 |