Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Trimethoxysilane → (3-((2-Methoxyethoxy)methoxy)-2-methylpropyl)trimethoxysilane
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Trimethoxysilane | HCID 17215 | — |
| 반응물 | 2-Methyl-4,6,9-trioxa-1-decene | HCID 4382900 | — |
| 촉매 | Platinate(2-), hexachloro-, hydrogen, hydrate (1:2:1), (OC-6-11)- | HCID 16211507 | — |
| 용매 | Tetrahydrofuran | HCID 8028 | — |
| 생성물 | (3-((2-Methoxyethoxy)methoxy)-2-methylpropyl)trimethoxysilane | HCID 86690069 | 60% |
반응 단계
Into a 200-ml flask, 8.01 g (50% by mol) of 2-methyl-4,9,6-trioxa-1-decene, 0.026 g (0.05% by mol) of hexachloroplatinic(IV) acid hydrate, and 100 g of tetrahydrofuran were charged. Into the mixed solution, 7.94 g (65% by mol) of trimethoxysilane was added dropwise under a nitrogen stream with stirring with a magnetic stirrer. After the addition, the mixture was reacted at ambient temperature for 24 hours. Then, the reaction mixture was distilled to afford 8.47 g of (3-((2-methoxyethoxy)methoxy)-2-methylpropyl)trimethoxysilane (corresponding to the compound of Formula (A-29)).
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US09196484B2 |
| 출처 데이터셋 | uspto-grants-2015_11 |
| ORD ID | ord-5a73cde3f8a94288980f98938799ef44 |
| 출처 메모 | uspto-grants-2015_11 |