Acrylonitrile → HCID 11724229, compound

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The title compound was prepared from 1-(4-chloro-phenacyl)-quinolinium bromide (82.3 mg, 0.227 mmol), tetrapyridinecobalt(II) dichromate (151 mg, 0.248 mmol), sodium bicarbonate (49.5 mg, 0.589 mmol), acrylonitrile (100 μL, 1.52 mmol), and N,N-dimethylformamide (2.0 mL), similar to Example 1b, and yielded 15.6 mg (20%) as a yellow solid. 1H NMR (CDCl3): 8.03 (m, 3H), 7.86 (dd, J=7.97, 1.64 Hz, 1H), 7.75 (d, J=9.34 Hz, 1H), 7.68 (d, J=9.34 Hz, 1H), 7.62 (ddd, J=8.31, 7.07, 1.72 Hz, 1H), 7.55 (m, 3H), 7.41 (s, 1H).

Provenance & Evidence