Acrylonitrile → HCID 10470636, compound

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The title compound was prepared from 4-methyl-1-phenacyl-quinolinium bromide (86.5 mg, 0.253 mmol), tetrapyridinecobalt(II) dichromate (163 mg, 0.263 mmol), sodium bicarbonate (53.6 mg, 0.638 mmol), acrylonitrile (100 μL, 1.52 mmol), and N,N-dimethylformamide (2.0 mL), similar to Example 1b, and yielded 30.0 mg (38%) as a yellow solid. 1H NMR (CDCl3): 8.12 (m, 1H), 8.06 (m, 2H), 7.98 (m, 1H), 7.69 (tt, J=7.37, 1.56 Hz, 1H), 7.53–7.64 (m, 5H) 7.38 (s, 1H), 2.72 (d, J=1.10 Hz, 3H).

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