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HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 722149Generated: October 25, 2026

Methyl 3,4-bis(bromomethyl)benzoate → Methyl 13-oxotricyclo[8.2.1.0(3),8]trideca-3(8),4,6-triene-5-carboxylate

https://huagongshe.com/reaction/722149

Reaction equation

Participants

RoleNameHCIDCharge
ReactantMethyl 3,4-bis(bromomethyl)benzoateHCID 2736819—
ReactantTricyclo[8.2.1.03,8]trideca-3,5,7-trien-13-oneHCID 5260406—
ProductMethyl 13-oxotricyclo[8.2.1.0(3),8]trideca-3(8),4,6-triene-5-carboxylateHCID 21882835—

Reaction Steps

Prepared using the procedure described for 11-oxo-5,6,7,8,9,10-hexahydro-6,9-methanobenzocyclooctene (Justus Liebigs Ann. Chem. 1961, 650, 115) using methyl 3,4-bis(bromomethyl)benzoate in place of 1,2-bis(bromomethyl)benzene.

Provenance & Evidence

DOI10.6084/m9.figshare.5104873.v1
Patent numberUS07138400B2
Source datasetuspto-grants-2006_11
ORD IDord-cbe197411cf04537958f141affd27194
Source noteuspto-grants-2006_11