3-Amino-4-methoxybenzoic acid → HCID 10403644, compound

HRID 722617Notes

Reaction equation

HRID 722617 reaction equation
[NH2:1][C:2]1[CH:3]=[C:4]([CH:8]=[CH:9][C:10]=1[O:11][CH3:12])[C:5]([OH:7])=O.[NH2:13][C:14]1[CH:19]=[C:18]([Br:20])[CH:17]=[CH:16][C:15]=1O>>[NH2:1][C:2]1[CH:3]=[C:4]([C:5]2[O:7][C:15]3[CH:16]=[CH:17][C:18]([Br:20])=[CH:19][C:14]=3[N:13]=2)[CH:8]=[CH:9][C:10]=1[O:11][CH3:12]

Participants

3

Reactant 2

HCID 178233-Amino-4-methoxybenzoic acidHCID 3518402-Amino-4-Bromophenol

Product 1

HCID 10403644HCID 10403644, compound

Procedure

Prepared by the method of Example 1a), from 3-amino-4-methoxybenzoic acid (1.84 g, 11.0 mmol) and 2-amino-4-bromophenol (2.0 g, 11.0 mmol) the subtitle compound was obtained (2.0 g, 55%). 1H NMR (CDCl3) δ 7.85(t, 1H), 7.64(dd, 1H), 7.58(d, 1H), 7.41(d, 1H), 6.90(d, 1H), 3.95(s, 3H).

Sources & evidence

ORD record
ord-a86fa797fb4747c68da019505bb932ae
Source dataset
uspto-grants-2006_11
Patent number
US07138425B2

Reaction notes

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