1-Bromooctadecane → HCID 58743406, compound

HRID 722809Notes

Reaction equation

HRID 722809 reaction equation
[CH2:1]([N:8]([C@@H:16]([CH3:19])[CH:17]=[O:18])[CH2:9][C:10]1[CH:15]=[CH:14][CH:13]=[CH:12][CH:11]=1)[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.Br[CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][CH2:32][CH2:33][CH2:34][CH2:35][CH2:36][CH2:37][CH3:38]>>[CH2:9]([N:8]([C@H:16]([C@H:17]([OH:18])[CH2:38][CH2:37][CH2:36][CH2:35][CH2:34][CH2:33][CH2:32][CH2:31][CH2:30][CH2:29][CH2:28][CH2:27][CH2:26][CH2:25][CH2:24][CH2:23][CH2:22][CH3:21])[CH3:19])[CH2:1][C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1)[C:10]1[CH:15]=[CH:14][CH:13]=[CH:12][CH:11]=1

Participants

3

Reactant 2

HCID 82181-BromooctadecaneHCID 11107860(S)-2-Dibenzylamino-propionaldehyde

Product 1

HCID 58743406HCID 58743406, compound

Procedure

According to the method of Example 26, from aldehyde 4 (350 mg, 1.38 mmol) and 1-bromooctadecane (1.15 g, 3.45 mmol), alcohol 46 was obtained as a colorless oil (395 mg, 56% yield).

Sources & evidence

ORD record
ord-7525fe7bc626495993438363d70a6f65
Source dataset
uspto-grants-2006_11
Patent number
US07138547B2

Reaction notes

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