1-Bromopentadecane → HCID 58743316, compound

HRID 722816Notes

Reaction equation

HRID 722816 reaction equation
[CH2:1]([N:8]([C@@H:16]([CH:19]([CH3:21])[CH3:20])[CH:17]=[O:18])[CH2:9][C:10]1[CH:15]=[CH:14][CH:13]=[CH:12][CH:11]=1)[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.Br[CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][CH2:32][CH2:33][CH2:34][CH2:35][CH2:36][CH3:37]>>[CH2:9]([N:8]([C@H:16]([C@H:17]([OH:18])[CH2:37][CH2:36][CH2:35][CH2:34][CH2:33][CH2:32][CH2:31][CH2:30][CH2:29][CH2:28][CH2:27][CH2:26][CH2:25][CH2:24][CH3:23])[CH:19]([CH3:21])[CH3:20])[CH2:1][C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1)[C:10]1[CH:15]=[CH:14][CH:13]=[CH:12][CH:11]=1

Participants

3

Reactant 2

HCID 123941-BromopentadecaneHCID 11140543HCID 11140543, compound

Product 1

HCID 58743316HCID 58743316, compound

Procedure

According to the method of Example 26, from aldehyde 14 (447 mg, 1.59 mmol) and 1-bromopentadecane (1.16 g, 4.0 mmol), alcohol 68 was obtained as a colorless oil (340 mg, 43% yield).

Sources & evidence

ORD record
ord-6926d99c549a4e93b92f83faa7f27671
Source dataset
uspto-grants-2006_11
Patent number
US07138547B2

Reaction notes

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