1-Bromopentadecane → HCID 58743412, compound

HRID 722817Notes

Reaction equation

HRID 722817 reaction equation
[CH2:1]([N:8]([C@@H:16]([C@@H:19]([CH3:22])[CH2:20][CH3:21])[CH:17]=[O:18])[CH2:9][C:10]1[CH:15]=[CH:14][CH:13]=[CH:12][CH:11]=1)[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.Br[CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][CH2:32][CH2:33][CH2:34][CH2:35][CH2:36][CH2:37][CH3:38]>>[CH2:9]([N:8]([C@H:16]([C@H:17]([OH:18])[CH2:38][CH2:37][CH2:36][CH2:35][CH2:34][CH2:33][CH2:32][CH2:31][CH2:30][CH2:29][CH2:28][CH2:27][CH2:26][CH2:25][CH3:24])[C@@H:19]([CH3:22])[CH2:20][CH3:21])[CH2:1][C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1)[C:10]1[CH:15]=[CH:14][CH:13]=[CH:12][CH:11]=1

Participants

3

Reactant 2

HCID 123941-BromopentadecaneHCID 11346977HCID 11346977, compound

Product 1

HCID 58743412HCID 58743412, compound

Procedure

According to the method of Example 26, from aldehyde 17 (470 mg, 1.59 mmol) and 1-bromopentadecane (0.63 mL, 3.18 mmol), alcohol 71 was obtained as a colorless oil (499 mg, 60% yield).

Sources & evidence

ORD record
ord-996b2f0af470422dbe342ae9f2b6f67e
Source dataset
uspto-grants-2006_11
Patent number
US07138547B2

Reaction notes

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