1-Bromopentadecane → HCID 58743250, compound

HRID 722818Notes

Reaction equation

HRID 722818 reaction equation
[CH2:1]([N:8]([C@@H:16]([CH2:19][C:20]1[CH:25]=[CH:24][C:23]([O:26][CH2:27][C:28]2[CH:33]=[CH:32][CH:31]=[CH:30][CH:29]=2)=[CH:22][CH:21]=1)[CH:17]=[O:18])[CH2:9][C:10]1[CH:15]=[CH:14][CH:13]=[CH:12][CH:11]=1)[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.Br[CH2:35][CH2:36][CH2:37][CH2:38][CH2:39][CH2:40][CH2:41][CH2:42][CH2:43][CH2:44][CH2:45][CH2:46][CH2:47][CH2:48][CH3:49]>>[CH2:27]([O:26][C:23]1[CH:22]=[CH:21][C:20]([CH2:19][C@H:16]([N:8]([CH2:9][C:10]2[CH:15]=[CH:14][CH:13]=[CH:12][CH:11]=2)[CH2:1][C:2]2[CH:3]=[CH:4][CH:5]=[CH:6][CH:7]=2)[C@H:17]([OH:18])[CH2:49][CH2:48][CH2:47][CH2:46][CH2:45][CH2:44][CH2:43][CH2:42][CH2:41][CH2:40][CH2:39][CH2:38][CH2:37][CH2:36][CH3:35])=[CH:25][CH:24]=1)[C:28]1[CH:29]=[CH:30][CH:31]=[CH:32][CH:33]=1

Participants

3

Reactant 2

HCID 123941-BromopentadecaneHCID 15248596HCID 15248596, compound

Product 1

HCID 58743250HCID 58743250, compound

Procedure

According to the method of Example 26, from aldehyde 20 (597 mg, 1.37 mmol) and 1-bromopentadecane (999 mg, 3.43 mmol), alcohol 74 was obtained as a colorless oil (496 mg, 56% yield).

Sources & evidence

ORD record
ord-d5acb74b46394dc99c2d010ad3f84c9e
Source dataset
uspto-grants-2006_11
Patent number
US07138547B2

Reaction notes

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