1-Bromopentadecane → HCID 58743258, compound

HRID 722819Notes

Reaction equation

HRID 722819 reaction equation
[CH2:1]([N:8]([C@@H:16]([CH2:19][CH2:20][CH2:21][N:22]([CH2:30][C:31]1[CH:36]=[CH:35][CH:34]=[CH:33][CH:32]=1)[CH2:23][C:24]1[CH:29]=[CH:28][CH:27]=[CH:26][CH:25]=1)[CH:17]=[O:18])[CH2:9][C:10]1[CH:15]=[CH:14][CH:13]=[CH:12][CH:11]=1)[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.Br[CH2:38][CH2:39][CH2:40][CH2:41][CH2:42][CH2:43][CH2:44][CH2:45][CH2:46][CH2:47][CH2:48][CH2:49][CH2:50][CH2:51][CH3:52]>>[CH2:23]([N:22]([CH2:21][CH2:20][CH2:19][C@H:16]([N:8]([CH2:9][C:10]1[CH:15]=[CH:14][CH:13]=[CH:12][CH:11]=1)[CH2:1][C:2]1[CH:3]=[CH:4][CH:5]=[CH:6][CH:7]=1)[C@H:17]([OH:18])[CH2:52][CH2:51][CH2:50][CH2:49][CH2:48][CH2:47][CH2:46][CH2:45][CH2:44][CH2:43][CH2:42][CH2:41][CH2:40][CH2:39][CH3:38])[CH2:30][C:31]1[CH:32]=[CH:33][CH:34]=[CH:35][CH:36]=1)[C:24]1[CH:29]=[CH:28][CH:27]=[CH:26][CH:25]=1

Participants

3

Reactant 2

HCID 123941-BromopentadecaneHCID 12122905HCID 12122905, compound

Product 1

HCID 58743258HCID 58743258, compound

Procedure

According to the method of Example 26, from aldehyde 23 (503 mg, 1.05 mmol) and 1-bromopentadecane (768; mg, 2.64 mmol), alcohol 77 was obtained as a colorless oil (350 mg, 48% yield).

Sources & evidence

ORD record
ord-41528c4e605d47978822c49df35ca2a2
Source dataset
uspto-grants-2006_11
Patent number
US07138547B2

Reaction notes

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