HuagongsheHuagongshe Chemistry Print Report · For research reference only
1,3-Propanediamine → 4-Iodobiphenyl
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 1,3-Propanediamine | HCID 428 | — |
| Reactant | Sodium Iodide | HCID 5238 | — |
| Reactant | 4-Bromobiphenyl | HCID 7101 | — |
| Solvent | 1-Pentanol | HCID 6276 | — |
| Product | 4-Iodobiphenyl | HCID 15322 | — |
Reaction Steps
30 g of 4-bromobiphenyl is dissolved in 40 mL of n-pentanol. 2 equivalents of sodium iodide and 10 mole % of 1,3-propanediamine are added to the 4-bromobiphenyl solution. The reaction mixture is refluxed at 130° C. for sixteen (16) hours to produce 4-iodobiphenyl, as shown in reaction scheme (5).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US07138555B2 |
| Source dataset | uspto-grants-2006_11 |
| ORD ID | ord-e26975268c1443fcb894981069a57230 |
| Source note | uspto-grants-2006_11 |