HCID 56992784, Verbindung → HCID 57076224, Verbindung

HRID 722887Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 722887
[C:1]([O:5][C:6](=[O:21])[CH2:7][C@@H:8]([CH2:17][N:18]=[N+:19]=[N-:20])[CH2:9][C@H:10]([CH3:16])[CH2:11][CH2:12][CH2:13][CH2:14][CH3:15])([CH3:4])([CH3:3])[CH3:2].C(OC(=O)C[C@@H](COS(C1C=CC(C)=CC=1)(=O)=O)C[C@@H](C)CCCCC)(C)(C)C>>[C:1]([O:5][C:6](=[O:21])[CH2:7][C@@H:8]([CH2:17][N:18]=[N+:19]=[N-:20])[CH2:9][C@@H:10]([CH3:16])[CH2:11][CH2:12][CH2:13][CH2:14][CH3:15])([CH3:3])([CH3:4])[CH3:2]

Komponenten

3

Edukt 2

HCID 56992784HCID 56992784, VerbindungHCID 57302665HCID 57302665, Verbindung

Produkt 1

HCID 57076224HCID 57076224, VerbindungAusbeute 96 %

Versuchsvorschrift

A procedure similar to that used to prepare compound 160 was used except (3S,5S)-5-methyl-3-(toluene-4-sulfonyloxymethyl)-decanoic acid tert-butyl ester 168 (4.155 g, 9.74 mmol) was used as a reactant to give 169 as an oil (2.77 g, 96%). MS (APCI) m/z 270 (M+−27, 30%, —N2), 214 (M+−87, 100%, -tBu, —N2).

Quellen und Nachweise

ORD-Eintrag
ord-83b249d520b14b7d86141070785fdecd
Quelldatensatz
uspto-grants-2006_11
Patentnummer
US07138542B2

Notizen zur Reaktion

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