HuagongsheHuagongshe Chemistry Print Report · For research reference only
(2R,3S,4R,5R)-2,3,4,5,6-pentahydroxyhexanal → (2R,3S,4R,5R)-2,3,4,5,6-pentahydroxyhexanal
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | (2R,3S,4R,5R)-2,3,4,5,6-pentahydroxyhexanal | HCID 107526 | — |
| Reactant | HCID 9920605 | HCID 9920605 | — |
| Product | (2R,3S,4R,5R)-2,3,4,5,6-pentahydroxyhexanal | HCID 107526 | 3% |
| Product | 1-BENZOYLPYRROLIDINE | HCID 966800 | — |
Reaction Steps
It has been found that presence of 2–3% glucose in the reaction mixture increases the yield. As shown in table 7, 73% of N-benzoyl-3-hydroxypyrrolidine can be obtained by hydroxylation of N-benzoylpyrrolidine (2 mM) with 3.9 g/L of cells of HXN-200 in the presence of glucose (3%).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US07141412B2 |
| Source dataset | uspto-grants-2006_11 |
| ORD ID | ord-6ca740afb7ae4d8393dd5c085f1ffbf2 |
| Source note | uspto-grants-2006_11 |