Ethanol, 2-amino-, 1-nitrate, nitrate (1:1) → HCID 54044801, compound

HRID 725127Notes

Reaction equation

HRID 725127 reaction equation
[C:1]([NH:4][C@H:5]([CH2:9][C:10](=[O:15])[C:11]([CH3:14])([CH3:13])[CH3:12])[C:6](O)=[S:7])(=[O:3])[CH3:2].[N+]([O-])(O)=O.[N+:20]([O:23][CH2:24][CH2:25][NH2:26])([O-:22])=[O:21]>>[N+:20]([O:23][CH2:24][CH2:25][NH:26][C:6](=[S:7])[C@H:5]([NH:4][C:1](=[O:3])[CH3:2])[CH2:9][C:10](=[O:15])[C:11]([CH3:14])([CH3:13])[CH3:12])([O-:22])=[O:21]

Participants

3

Reactant 2

HCID 78397Ethanol, 2-amino-, 1-nitrate, nitrate (1:1)HCID 178475074HCID 178475074, compound

Product 1

HCID 54044801HCID 54044801, compoundYield 74.5%

Procedure

The procedures of Example 1 were analogously repeated using 0.70 g of (2R)-2-acetylamino-3-pivaloylthiopropionic acid and 574 mg of 2-nitrooxyethylamine nitrate to give 0.72 g of the title compound as colorless crystals.

Sources & evidence

ORD record
ord-f90d095383974b1ca5b3a15111868934
Source dataset
uspto-grants-1998_01
Patent number
US05705527

Reaction notes

Loading…