HuagongsheHuagongshe Chemistry Print Report · For research reference only
Phenol → Diphenyl carbonate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Phenol | HCID 996 | — |
| Reactant | Carbonic acid, methyl phenyl ester | HCID 139482 | — |
| Product | Diphenyl carbonate | HCID 7597 | — |
Reaction Steps
A stream 11 essentially containing all the non-reacted phenol, phenyl methyl carbonate and any possible diphenyl carbonate produced, the transesterification catalyst and a fraction of the dimethylcarbonate fed, is extracted from the bottom of the reaction section of column C1 so that the molar ratio, in this stream, between the dimethyl carbonate and the phenol is between 0.5 and 5, normally between 1.0 and 5.0. This fraction usually forms between about 10 and about 60% of the total dimethyl carbonate fed to column C1.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05705673 |
| Source dataset | uspto-grants-1998_01 |
| ORD ID | ord-96e8a11a429549a189d0f037b46aa719 |
| Source note | uspto-grants-1998_01 |