Methyl iodide → HCID 131720391, compound

HRID 726188Notes

Reaction equation

HRID 726188 reaction equation
[CH3:1][N:2]([CH3:14])[C:3]1[C:12]([CH3:13])=[CH:11][C:6]2N=C(C)[Se:9][C:5]=2[CH:4]=1.C[I:16]>C(Cl)(Cl)Cl>[I-:16].[CH3:14][N:2]([CH3:1])[C:3]1[C:12]([CH3:13])=[CH:11][C:6]2[C:3]([CH3:4])=[N+:2]([CH3:1])[Se:9][C:5]=2[CH:4]=1

Participants

4

Reactant 2

HCID 6328Methyl iodideHCID 86751946HCID 86751946, compound

Product 1

HCID 131720391HCID 131720391, compoundYield 187.4%

Reagents, catalysts & solvents 1

HCID 6212ChloroformSolvent

Procedure

An autoclave was charged with 1.06 g of 6-dimethylamino-2,5-dimethylbenzoselenazole, 2.42 g of methyl iodide and 45 ml of chloroform. Then, the air in the autoclave was displaced by argon gas and the tube was sealed. After carrying out the reaction at 80° C. for 8 days, the solvent was distilled off and the residue was washed with diethyl ether, giving 1.55 g of 6-dimethylamino-2,3,5-trimethylbenzoselenazolenium iodide as pale yellow solids (yield 94%).

Workup

  1. customthe tube was sealed
  2. customthe reaction at 80° C. for 8 days
  3. distillationthe solvent was distilled off
  4. washthe residue was washed with diethyl ether

Sources & evidence

ORD record
ord-6672694b2ffe4a74a667e7e703dc2d32
Source dataset
uspto-grants-1998_01
Patent number
US05708181

Reaction notes

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