1-(2-Chlorophenyl)-1-cyclohexen-4-one → 4-(2-Chlorophenyl)cyclohexanone

HRID 727213Notes

Reaction equation

HRID 727213 reaction equation
[Cl:1][C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][C:3]=1[C:8]1[CH2:13][CH2:12][C:11](=[O:14])[CH2:10][CH:9]=1>[Pd].C(O)C>[Cl:1][C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][C:3]=1[CH:8]1[CH2:9][CH2:10][C:11](=[O:14])[CH2:12][CH2:13]1

Participants

4

Reactant 1

HCID 197051921-(2-Chlorophenyl)-1-cyclohexen-4-one

Product 1

HCID 197052584-(2-Chlorophenyl)cyclohexanone

Reagents, catalysts & solvents 2

HCID 23938PalladiumCatalystHCID 702EthanolSolvent

Procedure

This compound is prepared in a manner analogous to that of Step C of Example 2 by the hydrogenation of 6.5 grams (0.026 mole) of 1-(2-chlorophenyl)-1-cyclohexen-4-one in the presence of 0.4 gram (catalyst) of 10% palladium on charcoal in 50 mL of ethanol, yielding 4-(2-chlorophenyl)cyclohexanone.

Sources & evidence

ORD record
ord-b589d333660e4fc08d5e62957bcb4de1
Source dataset
uspto-grants-1998_01
Patent number
US05712281

Reaction notes

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