HCID 14989151, compound → HCID 14989163, compound

HRID 728403Notes

Reaction equation

HRID 728403 reaction equation
[CH3:1][C:2]([C:5]1[CH:6]=[C:7]([S:16][CH:17]([CH3:21])[C:18](=[O:20])[CH3:19])[CH:8]=[C:9]([C:12]([CH3:15])([CH3:14])[CH3:13])[C:10]=1[OH:11])([CH3:4])[CH3:3].[CH3:22][Li]>>[CH3:4][C:2]([C:5]1[CH:6]=[C:7]([S:16][CH:17]([CH3:21])[C:18]([OH:20])([CH3:22])[CH3:19])[CH:8]=[C:9]([C:12]([CH3:13])([CH3:15])[CH3:14])[C:10]=1[OH:11])([CH3:1])[CH3:3]

Participants

3

Reactant 2

HCID 14989151HCID 14989151, compoundHCID 178418348HCID 178418348, compound

Product 1

HCID 14989163HCID 14989163, compound

Procedure

The ketone of Example 8 is reacted with methyl lithium by the method of Example 17 to give the title compound.

Sources & evidence

ORD record
ord-8162b8064fbe4fd4b7d023ed7771049e
Source dataset
uspto-grants-1991_09
Patent number
US05047593

Reaction notes

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