HCID 86745055, compound → HCID 178481964, compound

HRID 728522Notes

Reaction equation

HRID 728522 reaction equation
[F:1][B-:2]([F:5])([F:4])[F:3].CN(C)C(=S)N(C)C.CN(C)C(=S)N(C)C.[CH3:22][N+:23]1[N:24]=[C:25]([S-:40])[N:26]([C:34]2[CH:39]=[CH:38][CH:37]=[CH:36][CH:35]=2)[C:27]=1[C:28]1[CH:33]=[CH:32][CH:31]=[CH:30][CH:29]=1>CO>[F:1][B-:2]([F:5])([F:4])[F:3].[CH3:22][N+:23]1[N:24]=[C:25]([S-:40])[N:26]([C:34]2[CH:35]=[CH:36][CH:37]=[CH:38][CH:39]=2)[C:27]=1[C:28]1[CH:33]=[CH:32][CH:31]=[CH:30][CH:29]=1.[CH3:22][N+:23]1[N:24]=[C:25]([S-:40])[N:26]([C:34]2[CH:35]=[CH:36][CH:37]=[CH:38][CH:39]=2)[C:27]=1[C:28]1[CH:33]=[CH:32][CH:31]=[CH:30][CH:29]=1

Participants

4

Reactant 2

HCID 86745055HCID 86745055, compoundHCID 178481963HCID 178481963, compound

Product 1

HCID 178481964HCID 178481964, compoundYield 91%

Reagents, catalysts & solvents 1

HCID 887MethanolSolvent2×

Procedure

Aurous bis(tetramethylthiourea) tetrafluoroborate (0.201 g, prepared as described above) was dissolved in 3 mL methanol at room temperature and added dropwise to 1-methyl-4,5-diphenyl-1,2,4-triazolium-3-thiolate (0.216 g) which was partly dissolved in 3 mL methanol at room temperature. The mixture was stirred for 10 minutes after the addition was complete, and then a white powder was filtered (91% yield). This product was soluble in acetone. The elemental analysis conformed to the formula for compound 10.

Workup

  1. additionafter the addition
  2. filtrationa white powder was filtered (91% yield)

Sources & evidence

ORD record
ord-ac992fd4f5f241d8931adf709d3f7b39
Source dataset
uspto-grants-1991_09
Patent number
US05049485

Reaction notes

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