Benzoyl Peroxide → HCID 14931580, compound

HRID 729773Notes

Reaction equation

HRID 729773 reaction equation
[CH3:1][C:2]1[C:11]2[C:6](=[CH:7][CH:8]=[CH:9][C:10]=2[CH3:12])[CH:5]=[CH:4][CH:3]=1.[Br:13]N1C(=O)CCC1=O.C(OOC(=O)C1C=CC=CC=1)(=O)C1C=CC=CC=1>C(Cl)(Cl)(Cl)Cl>[Br:13][CH2:1][C:2]1[C:11]2[C:6](=[CH:7][CH:8]=[CH:9][C:10]=2[CH3:12])[CH:5]=[CH:4][CH:3]=1

Participants

5

Reactant 3

HCID 7187Benzoyl PeroxideHCID 112871,8-DimethylnaphthaleneHCID 67184N-bromobutanimide

Product 1

HCID 14931580HCID 14931580, compound

Reagents, catalysts & solvents 1

HCID 5943Carbon TetrachlorideSolvent

Procedure

1,8-Dimethyl-naphthalene (1.30 g, 8.32 mmol) was dissolved in dry carbon tetrachloride (80 mL). To the reaction mixture was added N-bromosuccinimide (1.39 g, 7.82 mmol), dibenzoyl peroxide (6 mg, catalyst) and the reaction mixture was refluxing for 6 hours under nitrogen atmosphere. The reaction mixture was cooled to room temperature, a precipitate formed on cooling and the precipitate was separated by filtration. The filtrate was evaporated in vacuo to yield the title compound as a solid which was used in further steps without additional purification.

Workup

  1. temperaturethe reaction mixture was refluxing for 6 hours under nitrogen atmosphere
  2. customa precipitate formed
  3. temperatureon cooling
  4. customthe precipitate was separated by filtration
  5. customThe filtrate was evaporated in vacuo

Sources & evidence

ORD record
ord-b7c5ac11de0d4dcca72203ad22acf763
Source dataset
uspto-grants-2009_09
Patent number
US07582649B2

Reaction notes

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