HuagongsheHuagongshe Chemistry Print Report · For research reference only
Hydrogen Bromide → 1-Bromo-1-(3,4-dimethoxyphenyl)ethene
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Hydrogen Bromide | HCID 260 | — |
| Reactant | 4-Ethynyl-1,2-dimethoxybenzene | HCID 3616421 | — |
| Product | 1-Bromo-1-(3,4-dimethoxyphenyl)ethene | HCID 16085361 | 87% |
Reaction Steps
According to the General Procedure D, HBr (33% in acetic acid, 1.11 ml, 0.50 g, 6.17 mmol) and 3,4-dimethoxyphenylacetylene (1.00 g, 6.17 mmol) are converted to give after workup and chromatography (SiO2, PE/EE 5:1, Rf=0.41) the title compound (1.30 g, 5.35 mmol, 87%) as a brown oil; C10H11BrO2 (243.10).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US07589205B2 |
| Source dataset | uspto-grants-2009_09 |
| ORD ID | ord-26102aedb54047c39585e130260fd5c7 |
| Source note | uspto-grants-2009_09 |