HCID 22134479, compound → HCID 57721390, compound

HRID 733652Notes

Reaction equation

HRID 733652 reaction equation
[C:1]([C:5]1[CH:10]=[CH:9][CH:8]=[CH:7][C:6]=1[N:11]=[C:12]([C:14]1[CH:19]=[CH:18][CH:17]=[C:16]([C:20](=O)[CH3:21])[N:15]=1)[CH3:13])([CH3:4])([CH3:3])[CH3:2].[CH2:23]([O:43][C:44]1[C:50]([C:51]2[CH:56]=[CH:55][CH:54]=[CH:53][CH:52]=2)=[CH:49][C:47]([NH2:48])=[CH:46][C:45]=1[C:57]1[CH:62]=[CH:61][CH:60]=[CH:59][CH:58]=1)[CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][CH2:32][CH2:33][CH2:34][CH2:35][CH2:36][CH2:37][CH2:38][CH2:39][CH2:40][CH2:41][CH3:42]>C1(C)C=CC=CC=1>[C:1]([C:5]1[CH:10]=[CH:9][CH:8]=[CH:7][C:6]=1[N:11]=[C:12]([C:14]1[CH:19]=[CH:18][CH:17]=[C:16]([C:20](=[N:48][C:47]2[CH:46]=[C:45]([C:57]3[CH:58]=[CH:59][CH:60]=[CH:61][CH:62]=3)[C:44]([O:43][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][CH2:32][CH2:33][CH2:34][CH2:35][CH2:36][CH2:37][CH2:38][CH2:39][CH2:40][CH2:41][CH3:42])=[C:50]([C:51]3[CH:56]=[CH:55][CH:54]=[CH:53][CH:52]=3)[CH:49]=2)[CH3:21])[N:15]=1)[CH3:13])([CH3:4])([CH3:2])[CH3:3]

Participants

4

Reactant 2

HCID 22134479HCID 22134479, compoundHCID 22171929326613-30-3

Product 1

HCID 57721390HCID 57721390, compound

Reagents, catalysts & solvents 1

HCID 1140TolueneSolvent

Procedure

2-[1-(2-t-butylphenylimino)ethyl]-6-acetylpyridine (487 mg, 1.65 mmol), prepared according to the method described in US 2005/0059786, and 4-eicosanoxy-3,5-diphenylaniline (900 mg, 1.65 mmol) were dissolved in 50 ml of toluene. To this solution, 4 Å molecular sieves were added. After standing for 1 day the mixture was filtered. The solvent was removed in vacuo. The residue was crystallised from ethanol. The product A was isolated as an yellow solid (600 mg, 0.73 mmol, 44%).

Workup

  1. additionTo this solution, 4 Å molecular sieves were added
  2. filtrationthe mixture was filtered
  3. customThe solvent was removed in vacuo
  4. customThe residue was crystallised from ethanol

Sources & evidence

ORD record
ord-b807e71ec6b6462fafe0df8284735a5a
Source dataset
uspto-grants-2009_09
Patent number
US07589245B2

Reaction notes

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