Tetrafluoro-m-phenylenediamine dihydrochloride → HCID 68816217, compound

HRID 734150Notes

Reaction equation

HRID 734150 reaction equation
[N+:1]([C:4]1[CH:9]=[CH:8][C:7]([NH:10][CH2:11][CH:12]([OH:15])[CH2:13][OH:14])=[CH:6][C:5]=1[CH3:16])([O-])=O.C1(N)C(F)=C(F)C(F)=C(N)C=1F.[ClH:29].Cl>[Zn].[Cl-].[NH4+].O.C(O)C>[ClH:29].[ClH:29].[NH2:1][C:4]1[CH:9]=[CH:8][C:7]([NH:10][CH2:11][CH:12]([OH:15])[CH2:13][OH:14])=[CH:6][C:5]=1[CH3:16]

Participants

4

Reactant 2

HCID 149026Tetrafluoro-m-phenylenediamine dihydrochlorideHCID 23104601HCID 23104601, compound

Product 1

HCID 68816217HCID 68816217, compound

Reagents, catalysts & solvents 1

HCID 131726756ZINC ammonium chloride water ethanolCatalyst

Procedure

The 3-(4-nitro-3-methylphenylamino)propane-1,2-diol (9) obtained above was reduced with a boiling zinc/ammonium chloride/water/ethanol mixture. The corresponding amine was isolated in dihydrochloride form.

Sources & evidence

ORD record
ord-3ab4aab80cdb48e1b4f6f93578b840de
Source dataset
uspto-grants-2009_09
Patent number
US07591860B2

Reaction notes

Loading…