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3,5-Dimethylpiperidine → 1-[2-(2-Methoxy-4-nitrophenoxy)ethyl]-3,5-dimethylpiperidine
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | 3,5-Dimethylpiperidine | HCID 118259 | — |
| 反応物 | 1-(2-Bromoethoxy)2-methoxy-4-nitrobenzene | HCID 12937254 | — |
| 溶媒 | Dichloromethane methanol | HCID 21226129 | — |
| 生成物 | 1-[2-(2-Methoxy-4-nitrophenoxy)ethyl]-3,5-dimethylpiperidine | HCID 68819560 | — |
反応手順
Prepared analogously to Example 1.1.c. from 1-(2-bromoethoxy)-2-methoxy-4-nitrobenzene and 3,5-dimethylpiperidine. Yield: 0.4 g (48.1% of theory); C16H24N2O4 (M=308.38); calc.: molecular ion peak (M+H)+: 309; found: molecular ion peak (M+H)+: 309; Rf value: 0.5 (silica gel, dichloromethane/methanol (9:1)).
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US07592373B2 |
| 出典データセット | uspto-grants-2009_09 |
| ORD ID | ord-c7e9ff6246084a478ad9260b6a18f537 |
| 出典メモ | uspto-grants-2009_09 |