HuagongsheHuagongshe Chemistry Print Report · For research reference only
HCID 57842722, compound → 5-Amino-2-(tert-butylsulfonyl)benzonitrile
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | HCID 57842722 | HCID 57842722 | — |
| Reactant | 5-Amino-2-(ethanesulfonyl)benzonitrile | HCID 59838037 | — |
| Product | 5-Amino-2-(tert-butylsulfonyl)benzonitrile | HCID 57842823 | 96.1% |
Reaction Steps
Using a procedure analogous to that used to prepare 6B, 10A (609 mg, 2.27 mmol) was hydrogenated to give 10B (520 mg, 96%) as a white solid. 1H NMR (400 MHz, CD3OD) δ 1.35 (s, 9 H), 6.91 (dd, J=8.79, 2.20 Hz, 1 H), 7.07 (d, J=2.20 Hz, 1 H), 7.66 (d, J=8.79 Hz, 1 H).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US07592331B2 |
| Source dataset | uspto-grants-2009_09 |
| ORD ID | ord-ee7e4277679d4cc5b74368e19571996b |
| Source note | uspto-grants-2009_09 |