HuagongsheHuagongshe Chemistry Print Report · For research reference only
3-Isocyanatobenzonitrile → 4-Bromo-2,6-diethylphenethyl 3-cyanophenylcarbamate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 3-Isocyanatobenzonitrile | HCID 2733315 | — |
| Reactant | 4-Bromo-2-methylphenethyl 3-cyanophenylcarbamate | HCID 57842847 | — |
| Reactant | 2-(4-Bromo-2,6-diethylphenyl)ethanol | HCID 57842917 | — |
| Product | 4-Bromo-2,6-diethylphenethyl 3-cyanophenylcarbamate | HCID 57842786 | 86% |
Reaction Steps
Using a procedure analogous to that used to prepare 30C, 37C (280 mg, 1.95 mmol) was reacted with 3-isocyanatobenzonitrile to yield 37D (670 mg, 86%) as an yellow oil. 1H NMR (400 MHz, CD3OD) δ ppm 1.22 (t, J=7.58 Hz, 6 H) 2.73 (q, J=7.58 Hz, 4 H) 3.06 (t, J=8.1 Hz, 2 H) 4.21 (t, J=8.1 Hz, 2H) 7.19 (s, 2 H) 7.32-7.39 (m, 1 H) 7.40-7.50 (m, J=8.08, 8.08 Hz, 1 H) 7.66 (d, J=8.34 Hz, 1 H) 7.86 (s, 1 H).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US07592331B2 |
| Source dataset | uspto-grants-2009_09 |
| ORD ID | ord-eb5ca2644869409ab3fd33a11bae5fcc |
| Source note | uspto-grants-2009_09 |