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HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 736556Generated: October 29, 2026

4-Chlorobenzyl mercaptan → HCID 86588941, compound

https://huagongshe.com/reaction/736556

Reaction equation

Participants

RoleNameHCIDCharge
Reactant4-Chlorobenzyl mercaptanHCID 80409—
Reactant1-Ethynyl-4-fluorobenzeneHCID 522627—
ReactantSodiumHCID 5360545—
ProductHCID 86588941HCID 86588941—

Reaction Steps

A solution of 4-fluorophenylacetylene (0.02 mol) and 4-chlorobenzyl mercaptan (0.02 mol) and metallic sodium (0.02 g atom) was subjected to Procedure 2 to form (Z)-4-fluorostyryl 4-chlorobenzylsulfide. The title compound was obtained in 82% yield following oxidation. 1HNMR (CDC13) δ4.60 (2H, s), 6.68 (1H, d, JH,H=11.84), 7.18-7.60 (8H aromatic+1H ethylenic).

Provenance & Evidence

DOI10.6084/m9.figshare.5104873.v1
Patent numberUS07595347B2
Source datasetuspto-grants-2009_09
ORD IDord-50c5c6978f2d4188a34d11799afeefc0
Source noteuspto-grants-2009_09