HuagongsheHuagongshe Chemistry Print Report · For research reference only
Benzyl mercaptan → HCID 86588944, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Benzyl mercaptan | HCID 7509 | — |
| Reactant | Benzene, 1-bromo-4-ethynyl- | HCID 136603 | — |
| Reactant | Sodium | HCID 5360545 | — |
| Product | HCID 86588944 | HCID 86588944 | — |
Reaction Steps
A solution of 4-bromophenylacetylene (0.02 mol) and benzyl mercaptan (0.02 mol) and metallic sodium (0.02 g atom) was subjected to Procedure 2 to form (Z)-4-bromostyryl benzylsulfide. The title compound was obtained in 80% yield following oxidation. 1HNMR (CDC13) δ4.52 (2H, s), 6.80 (1H, d, JH,H=11.98), 7.18-7.59 (9H aromatic+1H ethylenic).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US07595347B2 |
| Source dataset | uspto-grants-2009_09 |
| ORD ID | ord-c682ca66c8d74337ad4067415f2e89d6 |
| Source note | uspto-grants-2009_09 |