HuagongsheHuagongshe Chemistry Print Report · For research reference only
Aniline → N-Allylaniline
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Aniline | HCID 6115 | — |
| Reactant | Allyl bromide | HCID 7841 | — |
| Reactant | 2,2,2-Trifluoro-N-phenylacetamide | HCID 67881 | — |
| Product | N-Allylaniline | HCID 68525 | — |
Reaction Steps
N-Allylaniline [NMR (200 MHz, DMSO-d6): δ3.68 (t, J=5.2 Hz, 2H); 5.10 (d, J=10.2 Hz, 1H); 5.23 (d, J=17.2 Hz, 1H); 5.78 (br s, 1H); 5.75-5.97 (m, 1H); 6.52 (t, J=7.3 Hz, 2H); 6.56 (d, J=7.8 Hz, 2H); 7.06 (t, J=7.3 Hz, 2H)] was prepared from aniline and allyl bromide via trifluoroacetanilide using the general method described by Hodge (Harland, P.A.; Hodge, P; Maughan, W.; Wildsmith, E. Synthesis, 1984, 941).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05552404 |
| Source dataset | uspto-grants-1996_09 |
| ORD ID | ord-627ef3d791574c29a32f02e4e0e88ebb |
| Source note | uspto-grants-1996_09 |