Iodo benzene diacetate → Bis(1-octyloxy-2,2,6,6-tetramethylpiperidin-4-yl) Azodicarboxylate

HRID 742616Notes

Reaction equation

HRID 742616 reaction equation
[NH:1]([C:25]([O:27][CH:28]1[CH2:33][C:32]([CH3:35])([CH3:34])[N:31]([O:36][CH2:37][CH2:38][CH2:39][CH2:40][CH2:41][CH2:42][CH2:43][CH3:44])[C:30]([CH3:46])([CH3:45])[CH2:29]1)=[O:26])[NH:2][C:3]([O:5][CH:6]1[CH2:11][C:10]([CH3:13])([CH3:12])[N:9]([O:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH3:22])[C:8]([CH3:24])([CH3:23])[CH2:7]1)=[O:4].C(O)(=O)C.C(O)(=O)C.IC1C=CC=CC=1>>[N:2]([C:3]([O:5][CH:6]1[CH2:11][C:10]([CH3:12])([CH3:13])[N:9]([O:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH3:22])[C:8]([CH3:23])([CH3:24])[CH2:7]1)=[O:4])=[N:1][C:25]([O:27][CH:28]1[CH2:29][C:30]([CH3:46])([CH3:45])[N:31]([O:36][CH2:37][CH2:38][CH2:39][CH2:40][CH2:41][CH2:42][CH2:43][CH3:44])[C:32]([CH3:34])([CH3:35])[CH2:33]1)=[O:26]

Participants

3

Reactant 2

HCID 12217721Iodo benzene diacetateHCID 15345986Bis(1-octyloxy-2,2,6,6-tetramethylpiperidin-4-yl) Hydrazine-1,2-dicarboxylate

Product 1

HCID 53726438Bis(1-octyloxy-2,2,6,6-tetramethylpiperidin-4-yl) Azodicarboxylate

Procedure

The procedure of Example 4 is repeated using 4.6 g of bis(1-octyloxy-2,2,6,6-tetramethylpiperidin-4-yl) hydrazine-1,2-dicarboxylate and 2.3 g of iodobenzene diacetate to afford 3.3 gg of the title compound as a pale yellow oil. NMR, IR and mass spectra analyses are consistent with the desired structure.

Sources & evidence

ORD record
ord-99425b3c8ba743078d1fd4b229b6f4ca
Source dataset
uspto-grants-1996_09
Patent number
US05554754

Reaction notes

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