Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | Water | HCID 962 | — |
| Reactant | Dodecanedinitrile | HCID 78301 | — |
| Solvent | Toluene | HCID 1140 | — |
| Product | 1,12-Dodecanediamine | HCID 17727 | 85% |
Reaction Steps
A mixture of 0.059 mmol RuHCl(H2)(PCy3)2, 2.87 mmol dodecanedinitrile, 5 mL water and 35 mL toluene was stirred in a Fisher-Porter tube at 80° C. under 860 kPa H2. After 22 hours, gc analysis showed that the dinitrile was completely converted and the product, 1,12-dodecanediamine, formed in 85% yield.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| Patent number | US05554778 |
|---|
| Source dataset | uspto-grants-1996_09 |
|---|
| ORD ID | ord-4eac579051e84295863251ed81f937f9 |
|---|
| Source note | uspto-grants-1996_09 |
|---|
