HCID 67670352, compound → HCID 572468, compound

HRID 743408Notes

Reaction equation

HRID 743408 reaction equation
[C:1]1([CH2:7][CH:8]=[CH:9][C:10]2[CH:15]=[CH:14][CH:13]=[CH:12][C:11]=2[O:16]CC2C=CC=CC=2)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[H][H]>C(O)C.[Pd]>[C:1]1([CH2:7][CH2:8][CH2:9][C:10]2[CH:15]=[CH:14][CH:13]=[CH:12][C:11]=2[OH:16])[CH:2]=[CH:3][CH:4]=[CH:5][CH:6]=1

Participants

5

Reactant 2

HCID 67670352HCID 67670352, compoundHCID 178418361HCID 178418361, compound

Product 1

HCID 572468HCID 572468, compoundYield 83%

Reagents, catalysts & solvents 2

HCID 23938PalladiumCatalystHCID 702EthanolSolvent

Procedure

The whole of this benzyl 2-(3-phenyl-1-propenyl)phenyl ether was treated with hydrogen in the presence of 100 mg of 5% w/w palladium-on-carbon in 40 ml of ethanol at room temperature for 3 hours. At the end of this time, insoluble materials were removed by filtration, and the filtrate was concentrated by distillation under reduced pressure, to give 0.230 g (yield 83%) of the title compound as a colorless oil.

Workup

  1. customAt the end of this time, insoluble materials were removed by filtration
  2. concentrationthe filtrate was concentrated by distillation under reduced pressure

Sources & evidence

ORD record
ord-29c8e3a369e34a0086a19b5c19baf3e4
Source dataset
uspto-grants-1996_09
Patent number
US05556864

Reaction notes

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