Barium Oxide Nanoparticle Dispersion → HCID 86749825, compound

HRID 743673Notes

Reaction equation

HRID 743673 reaction equation
[ClH:1].[CH3:2][O:3][C:4]1[CH:9]=[C:8]([CH3:10])[C:7]([S:11]([NH:14][C@H:15]([C:43]([NH:45][C@@H:46]([C:57]([N:59]2[CH2:64][CH2:63][CH2:62][CH2:61][CH2:60]2)=[O:58])[CH2:47][C:48]2[CH:53]=[CH:52][C:51]([C:54](=[NH:56])[NH2:55])=[CH:50][CH:49]=2)=[O:44])[CH2:16][C:17](=[O:42])[NH:18][C@@H:19]2[O:32][C@H:31]([CH2:33][O:34]C(=O)C)[C@@H:26]([O:27]C(=O)C)[C@H:21]([O:22]C(=O)C)[C@H:20]2[NH:38][C:39](=[O:41])[CH3:40])(=[O:13])=[O:12])=[C:6]([CH3:65])[C:5]=1[CH3:66].[O-2].[Ba+2]>C(Cl)(Cl)Cl.CO>[ClH:1].[CH3:2][O:3][C:4]1[CH:9]=[C:8]([CH3:10])[C:7]([S:11]([NH:14][C@H:15]([C:43]([NH:45][C@@H:46]([C:57]([N:59]2[CH2:60][CH2:61][CH2:62][CH2:63][CH2:64]2)=[O:58])[CH2:47][C:48]2[CH:53]=[CH:52][C:51]([C:54](=[NH:55])[NH2:56])=[CH:50][CH:49]=2)=[O:44])[CH2:16][C:17](=[O:42])[NH:18][C@@H:19]2[O:32][C@H:31]([CH2:33][OH:34])[C@@H:26]([OH:27])[C@H:21]([OH:22])[C@H:20]2[NH:38][C:39](=[O:41])[CH3:40])(=[O:13])=[O:12])=[C:6]([CH3:65])[C:5]=1[CH3:66]

Participants

5

Reactant 2

HCID 9855530Barium Oxide Nanoparticle DispersionHCID 86749827HCID 86749827, compound

Product 1

HCID 86749825HCID 86749825, compound

Reagents, catalysts & solvents 2

HCID 887MethanolSolvent2×HCID 6212ChloroformSolvent

Procedure

Compound 26 (1.0 g) was deacetylated as described above with barium oxide (210 mg) in chloroform and methanol (90 mL). Yield: 0.65 g. [α]D =+15.6° (c 1.013 in methanol)

Sources & evidence

ORD record
ord-9e146c4167d343b09b5e2c6cdea00eea
Source dataset
uspto-grants-1996_09
Patent number
US05556941

Reaction notes

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