Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Hydroxyamine hydrochloride → alpha-Oximino-3-pyridylacetamidoxime
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Hydroxyamine hydrochloride | HCID 443297 | — |
| 반응물 | Sodium Acetate | HCID 517045 | — |
| 반응물 | alpha-Oximino-3-pyridylacetonitrile | HCID 72747148 | — |
| 용매 | Ethanol | HCID 702 | — |
| 생성물 | alpha-Oximino-3-pyridylacetamidoxime | HCID 136341185 | — |
반응 단계
A mixture of alpha-oximino-3-pyridylacetonitrile (41.0 g, 279 mmol), hydroxylamine hydrochloride (21.5 g, 310 mmol) and sodium acetate (50.8 g, 620 mmol) in ethanol (99.9%, 500 ml) was refluxed for 4 h. After cooling, the precipitate was collected by filtration and dried. The precipitate contained the wanted product and sodium acetate (85 g, 168%); M+ : 180.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US05559138 |
| 출처 데이터셋 | uspto-grants-1996_09 |
| ORD ID | ord-f8971d3b14f743c288e668c4c05045d7 |
| 출처 메모 | uspto-grants-1996_09 |