Iodomethyl pivalate → HCID 88206344, compound

HRID 744866Notes

Reaction equation

HRID 744866 reaction equation
[NH2:1][C:2]1[S:3][CH:4]=[C:5](/[C:7](=[N:31]/[OH:32])/[C:8]([NH:10][CH:11]2[C:29](=[O:30])[N:13]3[C:14]([C:26]([O-:28])=[O:27])=[C:15]([CH2:18][O:19][C:20]([N:22]4[CH2:25][CH2:24][CH2:23]4)=[O:21])[CH2:16][S:17][C@H:12]23)=[O:9])[N:6]=1.[Na+].[C:34]([O:40][CH2:41]I)(=[O:39])[C:35]([CH3:38])([CH3:37])[CH3:36]>>[NH2:1][C:2]1[S:3][CH:4]=[C:5](/[C:7](=[N:31]/[OH:32])/[C:8]([NH:10][CH:11]2[C:29](=[O:30])[N:13]3[C:14]([C:26]([O:28][CH2:41][O:40][C:34](=[O:39])[C:35]([CH3:38])([CH3:37])[CH3:36])=[O:27])=[C:15]([CH2:18][O:19][C:20]([N:22]4[CH2:25][CH2:24][CH2:23]4)=[O:21])[CH2:16][S:17][C@H:12]23)=[O:9])[N:6]=1

Participants

3

Reactant 2

HCID 104401Iodomethyl pivalateHCID 88206416HCID 88206416, compound

Product 1

HCID 88206344HCID 88206344, compoundYield 54%

Procedure

The compound obtained in Example 8 and iodomethyl pivalate were reacted, whereby the title compound was obtained (yield: 54%).

Sources & evidence

ORD record
ord-5c4f0b430ea84128ba12c05b34c154c2
Source dataset
uspto-grants-1996_09
Patent number
US05559225

Reaction notes

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