Iodomethyl pivalate → HCID 88207860, compound

HRID 744867Notes

Reaction equation

[NH2:1][C:2]1[S:3][CH:4]=[C:5](/[C:7](=[N:32]/[OH:33])/[C:8]([NH:10][CH:11]2[C:30](=[O:31])[N:13]3[C:14]([C:27]([O-:29])=[O:28])=[C:15]([CH2:18][O:19][C:20]([N:22]4[CH2:26][CH2:25][CH2:24][CH2:23]4)=[O:21])[CH2:16][S:17][C@H:12]23)=[O:9])[N:6]=1.[Na+].[C:35]([O:41][CH2:42]I)(=[O:40])[C:36]([CH3:39])([CH3:38])[CH3:37]>>[C:35]([O:41][CH2:42][O:28][C:27]([C:14]1[N:13]2[C:30](=[O:31])[CH:11]([NH:10][C:8](=[O:9])/[C:7](/[C:5]3[N:6]=[C:2]([NH2:1])[S:3][CH:4]=3)=[N:32]\[OH:33])[C@H:12]2[S:17][CH2:16][C:15]=1[CH2:18][O:19][C:20]([N:22]1[CH2:26][CH2:25][CH2:24][CH2:23]1)=[O:21])=[O:29])(=[O:40])[C:36]([CH3:39])([CH3:38])[CH3:37]

Participants

Reactant 2

HCID 104401Iodomethyl pivalate

HCID 88207198HCID 88207198, compound

Product 1

HCID 88207860HCID 88207860, compoundYield 28%

Procedure

The compound obtained in Example 13 and iodomethyl pivalate were reacted, whereby the title compound was obtained (yield: 28%).

Sources & evidence

ORD record: ord-2fe04d97043c4f14885b8bfb00585118
Source dataset: uspto-grants-1996_09
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US05559225

Reaction notes

Loading…