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HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 745139Generated: November 1, 2026

Nitric Acid → 4-Nitrotoluene

https://huagongshe.com/reaction/745139

Reaction equation

Participants

RoleNameHCIDCharge
ReactantNitric AcidHCID 944—
Reactant2,3-DinitrotolueneHCID 11761—
SolventTolueneHCID 1140—
Product4-NitrotolueneHCID 7473—

Reaction Steps

Commercially, nitroaromatics, and particularly dinitrotoluene, are produced by the mixed acid nitration of toluene, the mixed acid being a mixture of concentrated sulfuric and concentrated nitric acid. In the production of dinitrotoluene process, for example, toluene is first nitrated to form mononitrotoluene and then separated from the spent acid aqueous phase. The crude mononitrotoluene is then dinitrated with fresh acid in a second nitration stage. As is known the dinitrotoluene product recovered from the dinitration reactor contains impurities, primarily nitrophenolics, such as nitrocresol and picric acid.

Provenance & Evidence

DOI10.6084/m9.figshare.5104873.v1
Patent numberUS04597875
Source datasetuspto-grants-1986_07
ORD IDord-006c4635e1e645ea87dc4f7c31f23f01
Source noteuspto-grants-1986_07