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HRID745339

反应详情

EQUATION

反应方程式

HRID 745339 的结构方程式

REACTANTS

反应物

2
结构：ClP(Cl)(Cl)(Cl)Cl
HCID24819

Phosphorus pentachloride

Cl5P

结构：CCOP(=O)(CCCCc1ccccc1)OCC
HCID13102400

未命名化合物

PRODUCTS

生成物

1
结构：CCOP(=O)(Cl)CCCCc1ccccc1
HCID15591238

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

1
结构：c1ccccc1
溶剂HCID241

Benzene

C6H6

PROCEDURE

实验过程

A mixture of diethyl(4-phenylbutyl)phosphonate (0.73 g., 2.6 mmole), benzene (10 ml.) and phosphorus pentachloride (1.0 eq.) is refluxed under argon for 30 minutes. The benzene and phosphorus oxychloride are removed in vacuo to give ethoxy(4-phenylbutyl)phosphinyl chloride.

WORKUP

后处理

  1. temperatureis refluxed under argon for 30 minutes
  2. customThe benzene and phosphorus oxychloride are removed in vacuo