HuagongsheHuagongshe Chemistry Print Report · For research reference only
Dimethylformamide → Ethyl 2-(2-benzoyloxyethoxyimino)-3-oxobutyrate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Dimethylformamide | HCID 6228 | — |
| Reactant | Potassium Carbonate | HCID 11430 | — |
| Reactant | 2-Bromoethyl Benzoate | HCID 523090 | — |
| Reactant | HCID 178472877 | HCID 178472877 | — |
| Solvent | Ethyl Acetate | HCID 8857 | — |
| Product | Ethyl 2-(2-benzoyloxyethoxyimino)-3-oxobutyrate | HCID 53765835 | 92.4% |
Reaction Steps
A mixture of ethyl 2-hydroxyimino-3-oxobutyrate (syn isomer, 15.7 g.), 2-bromoethyl benzoate (27.5 g.), potassium carbonate (20.7 g.), N,N-dimethylformamide (25 ml.) and ethyl acetate (25 ml.) was treated in a similar manner to that of Example A-(1) to give ethyl 2-(2-benzoyloxyethoxyimino)-3-oxobutyrate (syn isomer, 28 g.).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04598147 |
| Source dataset | uspto-grants-1986_07 |
| ORD ID | ord-df1fc7facfb94affb1376faa3d123edc |
| Source note | uspto-grants-1986_07 |