HuagongsheHuagongshe Chemistry Print Report · For research reference only
Phenol → 2-(Ethylthio)phenol
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Phenol | HCID 996 | — |
| Reactant | Diethyl disulfide | HCID 8077 | — |
| Catalyst | Zirconium chloride (ZrCl4), (T-4)- | HCID 9856075 | — |
| Solvent | Toluene | HCID 1140 | — |
| Product | 2-(Ethylthio)phenol | HCID 122407 | 46.7% |
Reaction Steps
A similar run using phenol (142 g, 1.51 moles), toluene (150 ml), zirconium tetrachloride (6.0 g, 0.026 moles), and ethyl disulfide (62.0 g, 0.50 moles) gave ortho-(ethylthio)phenol (36.0 g, 46% yield).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04599451 |
| Source dataset | uspto-grants-1986_07 |
| ORD ID | ord-e4887f21a3f74dd6bf3261b09ed5f067 |
| Source note | uspto-grants-1986_07 |