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HRID745743

反应详情

EQUATION

反应方程式

HRID 745743 的结构方程式

REACTANTS

反应物

2
结构：[N-]=[N+]=[N-].[Na+]
HCID33557

未命名化合物

结构：O=[N+]([O-])c1c([N+](=O)[O-])c([N+](=O)[O-])c([N+](=O)[O-])c([N+](=O)[O-])c1[N+](=O)[O-]
HCID12488953

Hexanitrobenzene

C6N6O12

PRODUCTS

生成物

1
结构：[N-]=[N+]=Nc1c([N+](=O)[O-])c([N+](=O)[O-])c([N+](=O)[O-])c([N+](=O)[O-])c1[N+](=O)[O-]
HCID13710295

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

1
结构：c1ccccc1
溶剂HCID241

Benzene

C6H6

PROCEDURE

实验过程

The reaction is conducted by stirring a benzene solution of hexanitrobenzene with a slight excess of sodium azide (aqueous solution) at 25° C. After separating and drying the benzene solution, the solvent is removed leaving pure pentanitrophenyl azide. Recrystallization from carbon tetrachloride gives either long, flat yellow prisms (α-form) or chunky, orange-yellow rosettes (β-form) of pentanitrophenyl azide.

WORKUP

后处理

  1. customAfter separating
  2. dry with materialdrying the benzene solution
  3. customthe solvent is removed