HCID 23311052, compound → 2-(Prop-2-yn-1-yl)hexanoic acid

HRID 745903Notes

Reaction equation

HRID 745903 reaction equation
[CH2:1]([C:8](C(OCC)=O)([CH2:14][C:15]#[C:16][CH3:17])[C:9]([O:11]CC)=[O:10])[C:2]1C=CC=C[CH:3]=1.C(C(CC#CC)C(O)=O)C1C=CC=CC=1>>[CH2:1]([CH:8]([CH2:14][CH2:15][CH2:16][CH3:17])[C:9]([OH:11])=[O:10])[C:2]#[CH:3]

Participants

3

Reactant 2

HCID 23311052HCID 23311052, compoundHCID 23311056HCID 23311056, compound

Product 1

HCID 1345982-(Prop-2-yn-1-yl)hexanoic acid

Procedure

Proceeding similarly, but replacing ethyl 2-carboethoxy-2-propargylhexanoate with ethyl 2-benzyl-2-carboethoxy-4-hexynoate, 2-benzyl-4-hexynoic acid is prepared.

Workup

  1. customis prepared

Sources & evidence

ORD record
ord-92f477823c474fa0b5dac1a494c3af2f
Source dataset
uspto-grants-1986_07
Patent number
US04602006

Reaction notes

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