HuagongsheHuagongshe Chemistry Print Report · For research reference only
P-Xylene → HCID 70416722, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | P-Xylene | HCID 7809 | — |
| Reactant | Sodium hydride | HCID 24758 | — |
| Reactant | 5-Bromo-2-furanecarboxylic acid | HCID 68511 | — |
| Reactant | HCID 5364682 | HCID 5364682 | — |
| Solvent | Acetic Acid | HCID 176 | — |
| Solvent | Water | HCID 962 | — |
| Product | HCID 70416722 | HCID 70416722 | — |
Reaction Steps
A mixture of 57.2 (0.300 mole) of 5-bromo-2-furoic acid, 121.0 g (0.45 mole) of cis-9-pentadecenol, 18.0 g (0.750 mole) of sodium hydride and 2 liters of p-xylene are heated to reflux for 48 hours. The mixture is allowed to cool, then is acidified with acetic acid and diluted with 2 liters of water. The organic layer is separated, dried, evaporated to dryness, and the residue recrystallized from hexane to give 5-(cis-9-pentadecenyloxy)-2-furoic acid.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04602099 |
| Source dataset | uspto-grants-1986_07 |
| ORD ID | ord-aa8e9c2421ac4708a2d23b5ff9f2fc36 |
| Source note | uspto-grants-1986_07 |