3,3-Bis(p-chlorophenyl)propionic acid → 3,3-Bis(4-chlorophenyl)prop-2-enoic acid

HRID 746223Notes

Reaction equation

HRID 746223 reaction equation
[Cl:1][C:2]1[CH:7]=[CH:6][C:5]([CH:8]([C:15]2[CH:20]=[CH:19][C:18]([Cl:21])=[CH:17][CH:16]=2)[CH2:9][C:10]([O:12]CC)=[O:11])=[CH:4][CH:3]=1.ClC1C=CC(C(C2C=CC(Cl)=CC=2)CC(O)=O)=CC=1>>[Cl:1][C:2]1[CH:3]=[CH:4][C:5]([C:8]([C:15]2[CH:16]=[CH:17][C:18]([Cl:21])=[CH:19][CH:20]=2)=[CH:9][C:10]([OH:12])=[O:11])=[CH:6][CH:7]=1

Participants

3

Reactant 2

HCID 756813,3-Bis(p-chlorophenyl)propionic acidHCID 13503444HCID 13503444, compound

Product 1

HCID 123695283,3-Bis(4-chlorophenyl)prop-2-enoic acid

Procedure

Prepared in a similar manner in 95% yield from ethyl 3,3-bis(p-chlorophenyl)propionate was 3,3-bis(p-chlorophenyl)propionic acid, m.p. 190°-193° C.

Sources & evidence

ORD record
ord-c37568a37962462199e1cb4e0ac6ca8b
Source dataset
uspto-grants-1986_07
Patent number
US04603145

Reaction notes

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