Benzaldehyde → 2,2,2-Trichloro-1-phenylethanol

HRID 746312ノート

反応式

HRID 746312 の反応式
C(=O)C1C=CC=CC=1.[CH:9](=[O:18])[C:10]1[CH:15]=[CH:14][C:13]([O:16][CH3:17])=[CH:12][CH:11]=1.[Cl:19][C:20]([CH:23]([OH:33])[C:24]1[CH:29]=[CH:28][CH:27]=[C:26]([N+]([O-])=O)[CH:25]=1)([Cl:22])[Cl:21]>>[Cl:19][C:20]([CH:23]([OH:33])[C:24]1[CH:25]=[CH:26][CH:27]=[CH:28][CH:29]=1)([Cl:21])[Cl:22].[Cl:19][C:20]([CH:9]([OH:18])[C:10]1[CH:15]=[CH:14][C:13]([O:16][CH3:17])=[CH:12][CH:11]=1)([Cl:22])[Cl:21]

参加物

5

反応物 3

HCID 240BenzaldehydeHCID 312444-MethoxybenzaldehydeHCID 27258143-Nitro-alpha-(trichloromethyl)benzenemethanol

生成物 2

HCID 161502,2,2-Trichloro-1-phenylethanolHCID 51779312,2,2-Trichloro-1-(4-methoxyphenyl)ethan-1-ol

実験手順

Following the procedure of Example I and substituting benzaldehyde, 4-anisaldehyde and other starting material compounds and substituting the reagents of Example II, there is obtained trichloromethylbenzyl alcohol, trichloromethyl-4-methoxybenzyl alcohol and the benzaldehyde corresponding to said starting material compound, respectively.

出典と根拠

ORDレコード
ord-c4adb5a068ea450888597dbb92e82d82
出典データセット
uspto-grants-1986_07
特許番号
US04603227

反応ノート

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