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HRID747053

反应详情

EQUATION

反应方程式

HRID 747053 的结构方程式

REACTANTS

反应物

2
结构：CN(C)C=C1C(=O)CCCC1=O
HCID359353

2-[(Dimethylamino)methylene]-1,3-cyclohexanedione

C9H13NO2

结构：CC(C)(C)[Si](OCCC(=N)N)(c1ccccc1)c1ccccc1
HCID58841407

未命名化合物

PRODUCTS

生成物

1
结构：CC(C)(C)[Si](OCCC#N)(c1ccccc1)c1ccccc1
HCID10828716

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

1
结构：CCO
溶剂HCID702

Ethanol

C2H6O

PROCEDURE

实验过程

A Solution of 3-(tert-butyldiphenylsilyloxy) propanamidine (25 g, 77 mmol) and 2-((dimethylamino)methylene)cyclohexane-1,3-dione (12.8 g, 77 mmol) in 400 mL of dry EtOH was heated at 80° C. for 3 h. After cooling to room temperature, the solvent was evaporated. Flash chromatography (SiO2, EtOAc/hexane=1:1) gave the title compound as a white solid.

WORKUP

后处理

  1. customthe solvent was evaporated