HuagongsheHuagongshe Chemistry Print Report · For research reference only
Triethylamine → HCID 68459271, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Triethylamine | HCID 8471 | — |
| Reactant | Benzoic acid, 2-mercapto-, methyl ester | HCID 21009 | — |
| Reactant | HCID 22939311 | HCID 22939311 | — |
| Reactant | 6-Cyanopyridin-3-yl acetate | HCID 22939379 | — |
| Solvent | Toluene | HCID 1140 | — |
| Product | HCID 68459271 | HCID 68459271 | 29% |
Reaction Steps
A mixture of methyl thiosalicylate (0.58 g, 3.43 mmol), a mixture of 5-acetoxy-2-cyanopyridine and 3-acetoxy-2-cyanopyridine (0.60 g, 3.43 mmol), triethylamine (0.72 ml, 5.15 mmol) and toluene (100 ml) was refluxed for 48 hrs as described in Example 1. The solvent was concentrated under reduced pressure. The residue was recrystallized from ethanol to give the titled compound (0.30 g, 29%) as crystals.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US07399759B2 |
| Source dataset | uspto-grants-2008_07 |
| ORD ID | ord-eb747d87bc62457cb5fc264f7bc4f302 |
| Source note | uspto-grants-2008_07 |