HuagongsheHuagongshe Chemistry Print Report · For research reference only
Triethylamine → HCID 59750250, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Triethylamine | HCID 8471 | — |
| Reactant | Benzoic acid, 2-mercapto-, methyl ester | HCID 21009 | — |
| Reactant | HCID 22939271 | HCID 22939271 | — |
| Solvent | Toluene | HCID 1140 | — |
| Product | HCID 59750250 | HCID 59750250 | 97% |
Reaction Steps
A mixture of methyl thiosalicylate (1.3 g, 7.6 mmol), N-benzyl-6-cyano-2-pyridinecarboxamide (0.88 g, 3.7 mmol), triethylamine (2.0 ml, 14 mmol) and toluene (4 ml) was refluxed for 10 hrs as described in Example 1. After cooling, the precipitated crystals were collected by filtration and recrystallized from hexane-tetrahydrofuran to give the titled compound (0.97 g, 97%) as crystals.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US07399759B2 |
| Source dataset | uspto-grants-2008_07 |
| ORD ID | ord-e14801dcc9dc450691afb178f0aeb7a3 |
| Source note | uspto-grants-2008_07 |