HuagongsheHuagongshe Chemistry Print Report · For research reference only
Triethylamine → HCID 59750109, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Triethylamine | HCID 8471 | — |
| Reactant | Benzoic acid, 2-mercapto-, methyl ester | HCID 21009 | — |
| Reactant | 6-(Methylthio)nicotinonitrile | HCID 22939527 | — |
| Solvent | Toluene | HCID 1140 | — |
| Product | HCID 59750109 | HCID 59750109 | 31% |
Reaction Steps
5-Cyano-2-methylthiopyridine (2.26 g, 15.0 mmol) and methyl thiosalicylate (5.05 g, 30.0 mmol) were dissolved in toluene (100 ml), and triethylamine (6.3 ml, 45.0 mmol) was added thereto. The reaction mixture was refluxed for 48 hrs. The solvent was evaporated. The residue was recrystallized from ethanol to give the titled compound (1.30 g, 31%) as pale yellow crystals.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US07399759B2 |
| Source dataset | uspto-grants-2008_07 |
| ORD ID | ord-0ec8811a719e46ea9312ab8385674542 |
| Source note | uspto-grants-2008_07 |